The example configuration is missing half of Quad9's addresses.
# Some examples of DNS servers which may be used for DNS= and FallbackDNS=:
# Cloudflare: 1.1.1.1#cloudflare-dns.com 1.0.0.1#cloudflare-dns.com 2606:4700:4700::1111#cloudflare-dns.com 2606:4700:4700::1001#cloudflare-dns.com
# Google: 8.8.8.8#dns.google 8.8.4.4#dns.google 2001:4860:4860::8888#dns.google 2001:4860:4860::8844#dns.google
-# Quad9: 9.9.9.9#dns.quad9.net 2620:fe::fe#dns.quad9.net
+# Quad9: 9.9.9.9#dns.quad9.net 149.112.112.112#dns.quad9.net 2620:fe::fe#dns.quad9.net 2620:fe::9#dns.quad9.net
#DNS=
#FallbackDNS=@DNS_SERVERS@
#Domains=