Avoid null pointer dereference if error result lacks SQLSTATE.

Avoid null pointer dereference if error result lacks SQLSTATE.

Although error results received from the backend should always have
a SQLSTATE field, ones generated by libpq won't, making this code
vulnerable to a crash after, say, untimely loss of connection.
Noted by Coverity.

Oversight in commit 403a3d91c.  Back-patch to 9.5, as that was.