Fix overly tense optimization of PLpgSQL_func_hashkey: we must represent

Fix overly tense optimization of PLpgSQL_func_hashkey: we must represent
the isTrigger state explicitly, not rely on nonzero-ness of trigrelOid
to indicate trigger-hood, because trigrelOid will be left zero when compiling
for validation.  The (useless) function hash entry built by the validator
was able to match an ordinary non-trigger call later in the same session,
thereby bypassing the check that is supposed to prevent such a call.
Per report from Alvaro.

It might be worth suppressing the useless hash entry altogether, but
that's a bigger change than I want to consider back-patching.

Back-patch to 8.0.  7.4 doesn't have the problem because it doesn't
have validation mode.